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Creators/Authors contains: "Lindley, Brian M."

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  1. ; ; ; ; (, Inorganic Chemistry)
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  2. ; ; ; ; (, Inorganic Chemistry)
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  3. ; ; ; ; ; ; ; (, Chemical Science)
    A C–H bond activation strategy based on electrochemical activation of a metal hydride is introduced. Electrochemical oxidation of ( tBu4 PCP)IrH 4 ( tBu4 PCP is [1,3-( t Bu 2 PCH 2 )-C 6 H 3 ] − ) in the presence of pyridine derivatives generates cationic Ir hydride complexes of the type [( tBu4 PCP)IrH(L)] + (where L = pyridine, 2,6-lutidine, or 2-phenylpyridine). Facile deprotonation of [( tBu4 PCP)IrH(2,6-lutidine)] + with the phosphazene base tert -butylimino-tris(pyrrolidino)phosphorane, t BuP 1 (pyrr), results in selective C–H activation of 1,2-difluorobenzene (1,2-DFB) solvent to generate ( tBu4 PCP)Ir(H)(2,3-C 6 F 2 H 3 ). The overall electrochemical C–H activation reaction proceeds at room temperature without need for chemical activation by a sacrificial alkene hydrogen acceptor. This rare example of undirected electrochemical C–H activation holds promise for the development of future catalytic processes. 
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  4. ; ; ; ; ; ; ; (, Journal of the American Chemical Society)